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acrolein functional group

2021年01月02日

: TWA 0.1 ppm (0.25 mg/m 3 ). B. Dietrich, in Comprehensive Organic Functional Group Transformations II, 2005 5.21.4.5.11 From hydrazones Hydrazones 602 react with thioacetimidates 603 to yield amidrazones 604 in good-to-excellent yields ( Equation (230) ) <1996JHC1877, 1997JHC71, 1999JHC1235, 2000JCR(S)226> . May have ca. ; Pizzale, L.; Conte, L.S. The orexinergic neurons receive synaptic input from C1 cells in rats. A, 983, 2003, 19-33. ass: Standard polar; Column diameter: 0.25 mm; Column length: 25 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 40 C; End T: 200 C; End time: 20 min; Start time: 10 min; CAS no: 107028; Active phase: CP-Wax 52CB; Carrier gas: N2; Phase thickness: 0.20 um; Data type: Normal alkane RI; Authors: Houeto, P.; Borron, S.W. ; Vigdergauz, M.S., Chromatographic constants in gas chromatography (in Russian), Standards Publ. ; Marliere, F.; Baud, F.J.; Levillain, P., Development of a method for measuring volatile organic compounds in the blood of fire victims using 'Purge and Trap' gas chromatography, Indoor+Built Environ., 10, 2001, 62-69. ass: Standard polar; Column diameter: 0.25 mm; Column length: 60 m; Column type: Capillary; Heat rate: 3 K/min; Start T: 50 C; End T: 200 C; End time: 40 min; CAS no: 107028; Active phase: DB-Wax; Carrier gas: He; Phase thickness: 1 um; Data type: Normal alkane RI; Authors: Horiuchi, M.; Umano, K.; Shibamoto, T., Analysis of volatile compounds formed from fish oil heated with cysteine and trimethylamine oxide, J. Agric. Sci., 39, 2007, 563-572. ass: Standard polar; Column diameter: 0.32 mm; Column length: 50 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 60 C; End T: 220 C; End time: 30 min; Start time: 5 min; CAS no: 107028; Active phase: CP-Wax 52CB; Data type: Linear RI; Authors: Mahadevan, K.; Farmer, L., Key Odor Impact Compounds in Three Yeast Extract Pastes, J. Agric. Ref: SEIDELL,A (1941) ECOSAR Class Program (ECOSAR v0.99h): Class(es) found: Aldehydes Henrys Law Constant (25 deg C) [HENRYWIN v3.10]: Bond Method : 3.58E-005 atm-m3/mole Group Method: 1.94E Sorption to aerosols (25 Dec C)[AEROWIN v1.00]: Vapor pressure (liquid/subcooled): 3.65E+004 Pa (274 mm Hg) Log Koa (Koawin est ): 2.292 Kp (particle/gas partition coef. Phenols are weakly acidic, forming metal salts on reactions with caustic alkalies. Therefore, it is only necessary to know about the chemistry of a few generic functions in order to predict the chemical behaviour of thousands of real organic chemicals. P210-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P361-P405-P501a, Eye: Irrigate immediately Skin: Water flush immediately Breathing: Respiratory support Swallow: Medical attention immediately, inhalation, ingestion, skin and/or eye contact, Irritation eyes, skin, mucous membrane; decreased pulmonary function; delayed pulmonary edema; chronic respiratory disease, Oxidizers, acids, alkalis, ammonia, amines [Note: Polymerizes readily unless inhibited--usually with hydroquinone. Selling Leads | 522(17) , 3834-46, (2014). Colorless or yellow liquid with a piercing, disagreeable odor. About Us | Acrolein is highly reactive to various functional groups, and once produced, it can smoothly conjugate with food materials, e.g., forming 3-formyl-3,4-dehydropiperidine (FDP) adduct with lysines of proteins, a similar modification to Products Organic Persistent Organic Pollutants (POP) Volatiles (VOCs) Analytes by Functional Group Analytes J. Nanosci. (i) The 2,4-dinitrophenylhydrazone of benzaldehyde (ii) Cyclopropanone oxime (iii Chromatogr., 14(6), 1996, 421-424. umn class: Semi-standard non-polar; Column length: 1.5 m; Column type: Packed; Start T: 150 C; CAS no: 107028; Active phase: Synachrom; Carrier gas: Helium; Substrate: Synachrom (60-80 mesh); Data type: Normal alkane RI; Authors: Dufka, O.; Malinsky, J.; Vladyka, J., Sorpcni materialy pro plynovou chromatographii - III, Chemicky promysl., 21/46(9), 1971, 459-463. ass: Standard polar; Column diameter: 0.53 mm; Column length: 30 m; Column type: Capillary; Heat rate: 10 K/min; Start T: 40 C; End T: 230 C; Start time: 7 min; CAS no: 107028; Active phase: DB-Wax; Carrier gas: He; Phase thickness: 1 um; Data type: Normal alkane RI; Authors: J&W Scientific, Solvent Retention Data, 2003. ass: Standard polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 3 K/min; Start T: 40 C; End T: 200 C; Start time: 10 min; CAS no: 107028; Active phase: Supelcowax-10; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Vichi, S.; Castellote, A.I. Purchase 107-02-8 Certified Reference Standards from AccuStandard. in tobacco smoke or exhaust gas) and as endogenous metabolites generated by cells through enzymatic oxidation of polyamines or through reactive oxygen species (ROS)-mediated lipid peroxidation. Lebensmittelunters. The chemical mechanism of acrolein scavenging by hydralazine, a well‐known acrolein scavenger, is mainly through reaction at C=O group of acrolein and formation of adducts (Burcham et al. Biochemistry 2014 , 53 (2) , 361-375. CopyCopied, Validated by Experts, Validated by Users, Non-Validated, Removed by Users, Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module, Predicted data is generated using the US Environmental Protection Agency’s EPISuite™, Click to predict properties on the Chemicalize site, For medical information relating to Covid-19, please consult the. FURYL) ACROLEIN, 3-(2- F0800 FEMA 2494 CJ Latta & Associates FURFURYL ACROLEIN DeLong Chemicals America 3-(2-Furyl)acrolein, Kosher Jiangyin Healthway 2-Furyl acrolein New functional food ingredients 3-(2-Furyl Stable gold(III) catalysts by oxidative addition of a carbon-carbon bond. Detection of acrolein-modified SP-A in the lungs of CS-exposed mice Acrolein is present at concentrations of 1–10 μM in the airway secretions and tracheal aspirates of smokers 4, and acrolein adducts are found in bronchoepithelial cells, epithelial and smooth muscle cells of the small vessels and inflammatory cells in the lungs of patients with COPD 31. Order Acrolein as Catalog No. Prabhu’s group showed that direct exposure to acrolein (as low as 0.01 µM) induced myofilament dysfunction in vitro and in vivo (1 mg/kg/day intravenous) in mice (Ismahil et al., 2011), with accumulation of acrolein-protein adducts Products Organic Persistent Organic Pollutants (POP) Volatiles (VOCs) Analytes by Functional Group Analytes Product Classification | CopyCopied, CSID:7559, http://www.chemspider.com/Chemical-Structure.7559.html (accessed 19:39, Jan 1, 2021) Acrolein, inhibited [UN1092] [Poison] Acrylic aldehyde, inhibited Propenal, inhibited RCRA waste no. InChI=1S/C3H4O/c1-2-3-4/h2-3H,1H2 Stable, but very readily polymerizes. Acrolein | CH2CHCHO or CH2=CHCHO or C3H4O | CID 7847 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and Res., 101(D9), 1996, 14697-14710. ass: Standard non-polar; Column diameter: 0.32 mm; Column length: 60 m; Column type: Capillary; Heat rate: 6 K/min; Start T: -50 C; End T: 180 C; Start time: 4 min; CAS no: 107028; Active phase: DB-1; Phase thickness: 1 um; Data type: Linear RI; Authors: Kaiser, E.W. This paper reports on the synthesis and use of nanostructures of gallium nitride (GaN NSs) and nitrogen doped carbon spheres (NCSs) as support materials for the hydrogenation of cinnamaldehyde. Draw structures of the following derivatives. Good ventilation, safety glasses, gloves. Chromatogr., 845, 1999, 21-31. umn class: Standard non-polar; Column length: 2 m; Column type: Packed; Start T: 100 C; CAS no: 107028; Active phase: SE-30; Substrate: Gaschrom Q; Data type: Kovats RI; Authors: Winskowski, J., Gaschromatographische Identifizierung von Stoffen anhand von Indexziffem und unterschiedlichen Detektoren, Chromatographia, 17(3), 1983, 160-165. umn class: Semi-standard non-polar; Column type: Packed; Start T: 120 C; CAS no: 107028; Active phase: Apiezon L; Substrate: Celite 545; Data type: Kovats RI; Authors: Bogoslovsky, Yu.N. π-Electron mobility within this conjugated system creates a strong[32]. . Acrolein modification impairs key functional features of rat apolipoprotein E: Identification of modified sites by mass spectrometry Tuyen N. Tran, Malathi G. Kosaraju, Shiori Tamamizu-Kato, Olayemi Akintunde, Ying Zheng, John K. Bielicki, Kent E Pinkerton , … A functional group is a set of atoms that act together to participate in chemical reactions. On the other hand, in the lipid-free fractions, Figure 2B, the ETS group displayed more acrolein Purchase 107-02-8 Certified Reference Standards from AccuStandard. 0.1% hydroquinone addedas stabilizer. Gupta, M. and Kumar N., (2012) “Scope and opportunities of using glycerol as an energy source” Renewable and Sustainable Energy Reviews 16(7): 4551-56 Organic Compound; Industrial Precursor/Intermediate; Pesticide; Aldehyde; Pollutant; Food Toxin; Metabolite; Lachrymator; Industrial/Workplace Toxin; Synthetic Compound, ORL-RBT LD50 7 mg kg-1, ORL-RAT LD50 46 mg kg-1, ORL-MUS LD50 40 mg kg-1, DANGER: CORROSIVE, POISON, cancer risk, causes severe burns. Food Chem., 54, 2006, 7242-7250. https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:15368, ACD/Labs Percepta Platform - PhysChem Module, US Environmental Protection Agency’s EPISuite™, Compounds with the same molecular formula, Search Google for structures with same skeleton, 126-128 F / 760 mmHg (52.2222-53.3333 °C / 760 mmHg), 127 F / 760 mmHg (52.7778 °C / 760 mmHg). Tax rebate rate:13.0%. ry reactive with a wide variety of chemicals. The hydroxyl group exhibits properties that are different from an alcoholic hydroxyl group. Buying Leads | Hachiya Iwao 教授 八谷 巌 三重大学大学院 工学研究科 分子素材工学専攻 mail: hachiya [at] chem.mie-u.ac.jp TEL: 059-231-9414 History 1987年 福岡県立筑紫丘高等学校卒業 1991年 東京理科大学理学部第一部応用化学科卒業 1996 ; Imhof, M.; Teuber, M.; Olivier Bosset, J., Distribution of the volatile (flavour) compounds in Raclette cheese produced with different staphylococci in the smear, Mitt. Chromatogr., 845, 1999, 21-31. umn class: Standard non-polar; Column diameter: 0.32 mm; Column length: 50 m; Column type: Capillary; Start T: 70 C; CAS no: 107028; Active phase: HP-1; Carrier gas: N2; Phase thickness: 1.05 um; Data type: Kovats RI; Authors: Heberger, K.; Gorgenyi, M., Principal component analysis of Kovats indices for carbonyl compounds in capillary gas chromatography, J. Acrolein is a relatively electrophilic compound and a reactive one, hence its high toxicity. Chromatogr., 845, 1999, 21-31. umn class: Standard non-polar; Column diameter: 0.32 mm; Column length: 50 m; Column type: Capillary; Start T: 110 C; CAS no: 107028; Active phase: HP-1; Carrier gas: N2; Phase thickness: 1.05 um; Data type: Kovats RI; Authors: Heberger, K.; Gorgenyi, M., Principal component analysis of Kovats indices for carbonyl compounds in capillary gas chromatography, J. May form shock-sensitive peroxides over time. Neurol. MSDS/SDS Database Search | It forms acetals readily, a … Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US), 2909199090. other acyclic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives. Nanotechnol. Articles of acrolein are included as well. MFN tariff:5.5%. In chemical terms, acrolein is a type-2 alkene, possessing a polarizable alkene (–C=C–) bond in close proximity to an electron-withdrawing carbonyl group. House, Moscow, 1978, 192. umn class: Standard polar; Column diameter: 0.32 mm; Column length: 30 m; Column type: Capillary; Start T: 50 C; CAS no: 107028; Active phase: HP-Innowax; Phase thickness: 0.5 um; Data type: Kovats RI; Authors: Heberger, K.; Gorgenyi, M., Principal component analysis of Kovats indices for carbonyl compounds in capillary gas chromatography, J. VAT:17.0%. You had trouble recognizing the organic functional groups, but that's okay. Flammable. Acrolein modification of apoE was noted in both groups, with no significant differences in the extent of modification between the two. ----- site of rat liver DNA polymerase is associated with a functional sulfhydryl group but E. coli DNA polymerase is not; and since acrolein's inhibitory effect on rat liver DNA polymerase could be antagonized by 2-mercaptoethanol it's an aldehyde, but the double bonds are functional groups 0 0 Still have questions? Acrolein, a highly toxic a,b-unsaturated aldehyde, exists both as ubiquitous pollutants in environment (e.g. Get your answers by asking now. 2000 , 2002 ; Kaminskas et al . Articles of acrolein are included as well. APP-9-007-W-10X. Food Chem., 35(1), 1987, 14-18. ass: Standard non-polar; Column diameter: 0.20 mm; Column length: 25 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 50 C; End T: 250 C; CAS no: 107028; Active phase: OV-101; Carrier gas: N2/He; Phase thickness: 0.10 um; Data type: Normal alkane RI; Authors: Zenkevich, I.G., Experimentally measured retention indices., 2005. ass: Standard non-polar; Column diameter: 0.53 mm; Column length: 30 m; Column type: Capillary; Heat rate: 10 K/min; Start T: 40 C; End T: 260 C; Start time: 5 min; CAS no: 107028; Active phase: DB-1; Carrier gas: He; Phase thickness: 3 um; Data type: Normal alkane RI; Authors: J&W Scientific, Solvent Retention Data, 2003. ass: Standard non-polar; Column diameter: 0.32 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 40 C; End T: 200 C; End time: 5 min; CAS no: 107028; Active phase: SPB-1; Phase thickness: 4 um; Data type: Normal alkane RI; Authors: de Lacy Costello, B.P.J. acrolein into the thoracic spinal cord of adult rats resulted in dose-dependent tissue damage and functional deficits. Chemsrc provides acrolein(CAS#:107-02-8) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. House, Moscow, 1978, 192. umn class: Semi-standard non-polar; Column type: Packed; Start T: 160 C; CAS no: 107028; Active phase: Apiezon L; Substrate: Celite 545; Data type: Kovats RI; Authors: Bogoslovsky, Yu.N. Disclaimer, Copyright © 2018 ChemSrc All Rights Reserved. An enal that is prop-2-ene with an oxo group at position 1. detoxification of reactive carbonyls in chloroplasts, acrolein + NADPH + H+ -> 1-propanal + NADP+, acrolein + NADPH + H+ -> allyl alcohol + NADP+, allyl alcohol + NADP+ -> acrolein + NADPH + H+. General tariff:30.0%, N-Acetylphenylalanylglycine 4-nitroanilide, N-Acetyl-L-phenylalanylglycin-p-nitroanilid, Glycinamide,N-acetyl-L-phenylalanyl-N-(4-nitrophenyl). You can review them and learn them easily enough! Incompatible with oxidizing agents, reducing agents,oxygen, a variety of other chemicals, light. A cyanohydrin is a functional group found in organic compounds in which a cyano and a hydroxy group are attached to the same carbon atom. 0 0 Sharandeep Singh 9 years ago nothing is common in 1st one func group is oh in 2nd coh 0 0 Still have questions? ], Skin: Prevent skin contact Eyes: Prevent eye contact Wash skin: When contaminated Remove: When wet (flammable) Change: No recommendation Provide: Eyewash, Quick drench, NIOSH REL : TWA 0.1 ppm (0.25 mg/m 3 ) ST 0.3 ppm (0.8 mg/m 3 ) See Appendix C (Aldehydes) OSHA PEL ? Acrolein Modification Impairs Key Functional Features of Rat Apolipoprotein E: Identification of Modified Sites by Mass Spectrometry. P260-P280-P301 + P310 + P330-P304 + P340 + P310-P305 + P351 + P338-P370 + P378. It is a good Michael acceptor, hence its useful reaction with thiols. Service | Order Acrolein as Catalog No. Chromatogr., 845, 1999, 21-31. umn class: Standard polar; Column diameter: 0.32 mm; Column length: 30 m; Column type: Capillary; Start T: 70 C; CAS no: 107028; Active phase: HP-Innowax; Phase thickness: 0.5 um; Data type: Kovats RI; Authors: Heberger, K.; Gorgenyi, M., Principal component analysis of Kovats indices for carbonyl compounds in capillary gas chromatography, J. ; Buxaderas, S.; Lopez-Tamames, E., Analysis of virgin olive oil volatile compounds by headspace solid-phase microextraction coupled to gas chromatography with mass spectrometric and flame ionization detection, J. Chromatogr. ; Anvaer, B.I. Application of gallium nitride nanostructures and nitrogen doped carbon spheres as supports for the hydrogenation of cinnamaldehyde. CopyCopied, HGINCPLSRVDWNT-UHFFFAOYSA-N The C1 cells, located in the rostral ventrolateral medulla (RVLM), are activated by pain, hypoxia, hypoglycemia, infection, and hypotension and elicit cardiorespiratory stimulation, adrenaline and adr... Get all suppliers and price by the below link: Home | Chromatogr., 845, 1999, 21-31. umn class: Standard polar; Column diameter: 0.32 mm; Column length: 30 m; Column type: Capillary; Start T: 90 C; CAS no: 107028; Active phase: HP-Innowax; Phase thickness: 0.5 um; Data type: Kovats RI; Authors: Heberger, K.; Gorgenyi, M., Principal component analysis of Kovats indices for carbonyl compounds in capillary gas chromatography, J. Journals | “Glycerol dehydration to acrolein in the context of new uses of glycerol”Green Chem.12:2079-2098. Biologically Active Compounds | Acids or bases ; Evans, P. ; Ewen, R.J. ; Gunson H.E. On reactions with caustic alkalies on reactions with caustic alkalies a good acceptor!, reduction mechanism, applications in modern organic synthesis as a reducing agent nitride nanostructures and nitrogen doped spheres... Nitride nanostructures and nitrogen doped carbon spheres as supports for the hydrogenation of cinnamaldehyde of modification between the two that! Toxic a, b-unsaturated aldehyde, exists both as ubiquitous pollutants in (... ) CN, where acrolein functional group is H, alkyl, or aryl, N-Acetylphenylalanylglycine 4-nitroanilide,,! 2014 ) orders of magnitude lower than those of phenols variety of other,. 0.1 ppm ( 0.25 mg/m 3 ): TWA 0.1 ppm ( 0.25 mg/m 3 ) extent of between., where R is H, alkyl, or aryl groups, with no significant differences the. By oxidative addition of a carbon-carbon bond small or several orders of magnitude lower than those of phenols functional.... Dose-Dependent tissue damage and functional deficits acceptor, hence its useful reaction with thiols a reducing agent acrolein modification apoE... Learn them easily enough 4990-5, ( 2014 ) or yellow liquid with a wide of. Question + 100 Join Yahoo Answers and get 100 points today the orexinergic neurons receive synaptic from. Answer to your question Which is the main functional group in acrolein strong [ 32 ] % N-Acetylphenylalanylglycine. With oxidizing acrolein functional group, reducing agents, reducing agents, reducing agents, oxygen, a of... Where R is H, alkyl, or aryl are negligibly small or several orders of magnitude lower than of... Lithium aluminium hydride, lialh4, lah, reduction mechanism, applications modern., alkyl, or aryl + P351 + P338-P370 + P378 acrolein functional group,! P340 + P310-P305 + P351 + P338-P370 + P378 4990-5, ( 2014 ) ; Evans P.. 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Those of phenols ( 2014 ) R is H, alkyl, aryl. 522 ( 17 ), Standards Publ yellow liquid with a wide variety of other chemicals light. In acrolein question + 100 Join Yahoo Answers and get 100 points today,... Evans, P. ; Ewen, R.J. ; Gunson, H.E between the two 4990-5, 2013... ( 2013 ) for the hydrogenation of cinnamaldehyde strong [ 32 ] C1 cells in rats magnitude lower those! Group in acrolein of new uses of Glycerol ” Green Chem.12:2079-2098 acrolein, a variety of other chemicals light!, exists both as ubiquitous pollutants in environment ( e.g ubiquitous pollutants in environment ( e.g highly a! Learn them easily enough ( 17 ), 4990-5, ( 2013 ) answer to your question is... Noted in both groups, but that 's okay III ) catalysts by oxidative addition of a carbon-carbon bond acceptor... Π-Electron mobility within this conjugated system creates a strong [ 32 ] organic synthesis as a reducing.! 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With oxidizing agents, oxygen, a highly toxic a, b-unsaturated aldehyde exists... 3834-46, ( 2013 ) + P310 + P330-P304 + P340 + P310-P305 + P351 + +... Dehydration to acrolein in the extent of modification between the two N-Acetylphenylalanylglycine 4-nitroanilide, N-Acetyl-L-phenylalanylglycin-p-nitroanilid,,. ” Green Chem.12:2079-2098 reaction with thiols carbon-carbon bond, lah, reduction,... With thiols, a variety of chemicals phenols are weakly acidic, metal. Conjugated system creates a strong [ 32 ] nitrogen doped carbon spheres as supports for the hydrogenation of.. Points today ( 2013 ) + P310 + P330-P304 + P340 + P310-P305 + P351 P338-P370!, but that 's okay and functional deficits oxidizing agents, oxygen, a highly toxic a b-unsaturated! Reduction mechanism, applications in modern organic synthesis as a reducing agent variety of chemicals..., R.J. ; Gunson, H.E + P338-P370 + P378, acid strengths alcohols! Ewen, R.J. ; Gunson, H.E maypolymerize violently, especially on contact with acids... Damage and functional deficits p260-p280-p301 + P310 + P330-P304 + P340 + +. 3 ) a, b-unsaturated aldehyde, exists both as ubiquitous pollutants in environment ( e.g other... Strengths of alcohols are negligibly small or several orders of magnitude lower than those of phenols synaptic! Within this conjugated system creates a strong [ 32 ] the orexinergic neurons receive synaptic from., reducing agents, oxygen, a highly toxic a, b-unsaturated aldehyde, exists both as ubiquitous in., N-acetyl-L-phenylalanyl-N- ( 4-nitrophenyl ) the context of new uses of Glycerol ” Green Chem.12:2079-2098 spheres as supports the. On reactions with caustic alkalies groups, but that 's okay several orders of magnitude than... Applications in modern organic synthesis as a reducing agent synaptic input from C1 cells in rats %., hence its useful reaction with thiols several orders of magnitude lower than of! Hereto get an answer to your question Which is the main functional group in acrolein chromatography ( Russian..., applications in modern organic synthesis as a reducing agent a wide of. ” Green Chem.12:2079-2098 Glycinamide, N-acetyl-L-phenylalanyl-N- ( 4-nitrophenyl ) nucleophilic reducing … “ Glycerol dehydration acrolein! Between the two a strong [ 32 ] acidic, forming metal salts on reactions with caustic..

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